Managed Aquifer Recharge (MAR) comprises a wide variety of systems in which water is intentionally introduced into an aquifer and subsequently recovered, e.g. for drinking water or irrigation purposes. The objective is i) to store excess water for times of less water availability and / or ii) to introduce an additional barrier for purification of water from different sources (e.g. surface water, treated waste water) for a specific use. Common MAR techniques in Europe are (Figure 1): river bank filtration (RBF) and artificial groundwater recharge – usually via ponded infiltration (AR). Riverbank filtration (RBF) has a long history as a process for generating safe water for human consumption in Europe. During industrialization in the 19th century drinking water facilities in England, the Netherlands and Germany started using bank filtered water due to the increasing pollution of the rivers. The systematic production of bank filtrates started around 1870-1890 (BMI 1975, 1985). Since then, RBF and in case of insufficient quantity, artificial groundwater recharge (AR) have been generally applied as a first barrier within the drinking water treatment chain. The most common and widely used method for artificial groundwater recharge (AR) are infiltration ponds (Asano, 2007). These simple surface spreading basins provide added benefits of treatment in the vadoze zone and subsequently in the aquifer. Advanced pretreatment of the infiltration water by coagulation, and advanced post-treatment of the recharged water, e.g. with activated carbon or ozonation became necessary in many cases after the 1960’s as the quality of the source water further decreased. Today the water supply of many European cities and densely populated areas relies on riverbank filtration or artificial recharge. Following Castany (1985), in France, the proportion of bank-filtered water reaches approximately 50% of the total drinking water production (Doussan et al., 1997). In the Netherlands 13% of drinking water is produced from infiltration of surface water, such as bank filtration and dune infiltration (Hiemstra et al., 2003). In Germany riverbank filtration and artificial groundwater recharge are used in the valleys of the rivers Rhein, Main, Elbe, Neckar, Ruhr, and in Berlin along the Havel and Spree (Grischek et al., 2002). In Berlin 75% of the drinking water is derived from riverbank filtration and artificially recharged groundwater (Schulze, 1977). Riverbank filtration is also applied in the United States as an efficient and low cost drinking water pre-treatment technology (Ray et al., 2002), also to improve the removal of surface water contaminating protozoa. In most applications, MAR is intended to act as a buffer in terms of water availability (quantity) and water quality. In general, the level of knowledge of natural treatment systems, notably in aquifers, is not as high as in engineered systems, because the biogeochemical environment in aquifers that modify water quality for sure, will vary in space and time (Dillon et al. 2008). The heterogeneity of the system, strengthens its buffer potential on the one hand, but makes it more difficult to describe and control on the other hand. Key parameters that determine the quantitative storage capacity of the system are the specific hydrogeology of the aquifer (e.g. transmissivity and porosity) and the clogging potential at the entry point of the recharge water (infiltration pond, well or river bank). Clogging occurs due to physical, chemical and biochemical processes and needs to be regarded carefully as it may reduce the systems performance substantially. From literature it is known, that increased clogging reduces the oxidation state of the clogging layer. At a bank filtration site at Lake Tegel, Berlin, it was observed that intensity and spatial distribution of clogging strongly depends on the extent and thickness of the unsaturated zone. Geochemical observations suggest, that atmosperic oxygen induces redox processes which lead to a reduction of the clogging layer (Wiese & Nützmann 2008). This is possibly due to the complex interaction of hydrochemical and biological processes within the uppermost centimetres of the aquifer (Hoffmann et al., 2006). If these processes are likewise found in AR system, they may be influenced as to minimize basin-cleaning efforts. This needs to be further investigated. Water quality aspects of MAR are governed by i) the quality of the infiltrated / injected water ii) physical straining of particulate and particle-bound substances, iii) adsorption and desorption, iv) biogeochemical degradation / deactivation processes within the aquifer, iv) the geochemical composition of the aquifer, and v) the quality of the ambient groundwater. The process most important for MAR applications is usually the physical straining of particulate and particlebound substances, lessening the effort for subsequent drinking water treatment. In Berlin, e.g. disinfection of drinking water can usually be avoided due to complete removal of pathogens during underground passage of up to 6 months. Cyanobacterial toxins (e.g. microcystins) that are primarily cell-bound are efficiently removed as well (Grützmacher et al. 2007). On the other hand there is still a lack of understanding under which circumstances microcystins or other cyanobacterial toxins like cylindrospermopsin (currently observed in growing quantities in Germany) are released, thus becoming potentially more mobile in the subsurface. Adsorption to the aquifer matrix contributes to the elimination of organic substances and heavy metals. Although this does not remove the substances completely, peak loads – e.g. from oil spills – are retarded and maximum concentrations reduced. In addition, sorption prolongs the detention time in the aquifer which multiplies the time for biodegradation. Biological degradation in the subsurface is responsible for the elimination of dissolved organic carbon (usually resulting from natural organic matter, NOM) and organic trace substances that occur at varying extent. Investigations have shown that the redox potential in the aquifer is decisive for the degree of elimination (Stuyfzand, 1998; Massmann et al. 2007). Due to increasingly sensitive analytical methods trace organics present in surface waters (e.g. pharmaceutical residues) have been detected in many MAR systems e.g in Berlin and the Netherlands (Massmann et al, 2007, Stuyfzand et al. 2007). Advanced numerical models including reactive flow and transport can simulate the complex interactions between the hydrogeochemical environment and degradation of trace organics (Greskowiak et al. 2006). However, so far this has only been applied for a limited number of compounds at very few sites. Further research is needed to apply these methods for risk assessment. A second method for predicting the removal of organic micropollutants is the more statistically based approach of linking substance properties (molecular weight, number of double bonds, number of aromatic rings, etc.) to biodegradation via quantitative structure-activity relationship (QSAR) type models. This has been applied successfully to other water treatment methods – a transfer to MAR is lacking so far. As MAR is a technology that relies on the interaction of natural processes framework conditions like climate and hydrogeology play an important role. There is a need for testing the transferability from central European conditions to other regions, and for an assessment, how temperature changes affect the system’s elimination capacity. With ongoing climate change, reducing precipitation in some regions of Europe and increasing peak flow events in others, MAR is the ideal technology to act as a buffer for quantity and quality. The European Water Supply and Sanitation Platform (www.wsstp.org) for example has identified MAR as a technology potentially fit for future challenges.

The project “Organic Trace Substances Relevant for Drinking Water – Assessing their Elimination through Bank Filtration (TRACE)” aims at giving an up-to-date overview of the potential risk resulting from the occurrence of chelating agents, perfluorinated compounds (PFCs) and selected pesticides in surface waters and to show if there is a potential for the substances to persist during bank filtration and artificial recharge. During the first phase of the project which is subject of this paper, a literature study was conducted addressing their occurrence (in the Berlin region and elsewhere), amounts produced as well as data on their persistence in the subsurface. This was the basis for a decision on the substance applied in the field scale experiments at the UBAs experimental field during the following project phase. Using freely available databases (e.g. ULIDAT, DIMDI, Tiborder) 1148 references were screened for their relevance to these topics, and 450 of these were classified as relevant. Of these, so far the 223 most important references have been compiled in an ACCESS database which comprises data on the data origin as well as on specific values (e.g. measured concentrations, amounts produced, use, main metabolites, sources, pathways in the environment). The database links this information so that output forms (“fact sheets”) can be created that summarize all data for one specific substance. The regarded substances were subsequently classified according to the criteria: usage / production, occurrence in surface water (if possible also in groundwater and bank filtrate), degradation potential, biological degradability, production of relevant metabolites and toxicity. For the chelating agents three substance groups were examined closely: aminocarboxylates, hydrocarboxylates and phosphonates (all other substance groups were found to be irrelevant due to total biodegradability). The aminocarboxylates are produced in highest numbers and occur most frequently (especially EDTA, PDTA, NTA and DTPA). There are, however, already extensive investigations on this field so that few knowledge gaps were identified. Hydrocarboxylates are produced in lesser amounts and for some ready biological degradability has been shown. For these reasons further investigations were not seen as a priority. Phosphonates produce relevant metabolites (phosphates that enhance eutrophication) and are produced in high amounts (> 1000 t/a). This substance group was therefore recommended for further investigations. Currently a variety of research projects cover the field of perfluorinated compounds (PFCs) that occur in aquatic environments world wide and whose toxicity and persistence is not yet clearly determined. Most investigations aim at the main substances of this group: PFOA and PFOS. These are, however, currently being replaced by shorter chained PFCs on which investigations are lacking. This substance group is therefore also of interest for further investigations. For the pesticides glyphosate and isoproturone high production rates and frequent occurrence in surface and groundwater world wide were determined. Due to this fact and to the presence of relevant metabolites (e.g. AMPA) as well as to limited knowledge on their fate during underground passage these substances were classified as highly interesting for further investigations.

Membrane processes stand as a promising technology to ensure a safe water supply at the community and the household levels. As the price of membranes has notably decreased over the last years, the market of membrane-based systems for decentralised applications has developed and diversified. In order to have a view of what the current market offers, 204 water companies were contacted and asked to characterise their Point-of-use (POU) or small-scale membrane systems, with a focus set on operation and maintenance, costs and energy requirements. Such study was not performed previously. With a 15% reply rate, the survey enables to identify the different market niches. That includes ceramic POU, organic POU, organic point-of-entries (POE), modular treatment units and emergency systems, whose technical characterization is further detailed in the Annex. Besides, the review of the marketed membrane modules reveals that ultrafiltration is the most available process. The survey also shows that the pre-treatment is a key parameter when considering options for decentralised water supply. As needs for sustainable solutions for small water supply are established, the membrane market is expected to grow and more standardised products to appear. The market evaluation can be summarized in Figure 1. Depending on the product niche, the membrane material and the filtration type, different degrees toward the market maturity are then highlighted. Such systems would be broadly applied in developed countries, but they represent also great potential for transition and developing countries. However, few systems designed for long-term operation with low-energy and low-chemical requirements exist yet. Therefore, the R&D identified within Techneau matches a non-fulfilled yet requirement.

Riverbank Filtration (RBF) is a valuable method for the (pre-)treatment of surface water for drinking water production. It has successfully been used in different parts of Europe for more than one century. The main intention of work package 5.2 of the TECHNEAU integrated project is to analyze the function and relevance of Riverbank Filtration (RBF) to enable sustainable water resources management, especially in developing and newly industrialized countries. A review on the attenuation capacity of RBF with a main focus on the significance for developing and newly industrialized countries is given in the D 5.2.3. This report (D 5.2.6) provides an overview on pathogen and organic trace compound content in water samples from the three TECHNEAU riverbank filtration (RBF) sites in Delhi, India. It is a follow up of the D 5.2.1 report that gives an introduction to the studies in Delhi, including regional information to water stressed mega city, environmental conditions at the three field sites and a summary of the hydrogeological investigations. Further information on hydrogeochemistry including inorganic ions (major ions, heavy metals and inorganic trace substabnces) and physicochemical parameters was submitted in D 5.2.2. The data published in this report represents water samples that have been collected during several field campaigns between May 2007 and March 2008 and analysed in different laboratories in India and Europe. Microbiological analysis includes faecal bacteria and indicator bacteria, bacteriophages and enteric viruses. For the analysis of organic contaminants, a non target GC-MS screening was performed as well as a quantitative analysis of pesticides and other trace pollutants.

The behaviour of residues of antibiotic drugs during bank filtration was studied at a field site in Berlin, Germany, where bank-filtered water is used for the production of drinking water. The neighbouring surface water used for bank filtration is under the influence of treated municipal wastewater. Seven out of 19 investigated antimicrobial residues were found in the surface water with median concentrations between 7 and 151 ng L¡1. Out of the seven analytes detected in the surface water only three (anhydroerythromycin, clindamycin and sulfamethoxazole) were found with median concentrations above their limits of quantitation in bank filtrate with a travel time of one month or less. With the exception of sulfamethoxazole, none of the 19 analytes were present in bank filtrate with a residence time larger than one month or in the water-supply well itself. Sulfamethoxazole found with a median concentration of 151 ng L¡1 in the surface water was the most persistent of all antimicrobial residues. Nevertheless, it was also removed by more than 98% and only found with a median concentration of 2 ng L¡1 in the water-supply well. The degradation of clindamycin and sulfamethoxazole appear to be redox-dependent. Clindamycin was eliminated more effi­ciently under oxic infiltration conditions while sulfamethoxazole was eliminated more rapidly under anoxic infiltration conditions. A slight preference for an improved degradation under oxic (clarithromycin and roxithromycin) or anoxic (anhydroerythromycin) conditions was also observed for the macrolide antibiotics. Nevertheless, all macrolides were readily removable by bank filtration both under oxic and anoxic conditions.

The use of groundwater for public water supply and irrigation has many benefits for water suppliers as well as for consumers. Over the last decades availability and consumption of this valuable resource has increased worldwide along with technical progress, but it has often been ignored that any abstraction of groundwater is an intervention in the balance of the natural water cycle. Managed aquifer recharge (MAR) present the double interest : 1. to be a possible technical answer to over-exploitation of groundwater reservoirs and can contribute to water resource preservation and possibly reuse 2. to provide a natural cleaning step to pre-treat surface water for drinking water supply, and therefore could contribute to reduce the need for highly sophisticated treatment methods which are cost intensive in installation and also in maintenance. In many parts of the world, such as low income countries, MAR offers the possibility to profit from the storage and purification capacity of natural soil/rock and to guarantee a sustainable management of groundwater. River bank filtration is an ancient and widely used method that currently provides water to a large number of population in EU (45% of Hungarian water supply, 16% of German water supply, 5% of The Netherland water supply). River bank filtration relies on natural conditions to operate efficiently and allow to produce a quality of water which, in some cases, doesn't required further treatment before distribution (such as in Berlin). There are now many evidences that global environmental conditions are progressively changing and may impact existing water supply scheme by bank filtration. The extensive study of bank filtration systems in different environmental settings (such as in India with higher temperature, different surface water quality, systems subject to monsoons and flooding …) will allow apprehending the limitation that current bank filtration systems may face, and highlight the possible need for adaptive strategies. The aim of this report is to document work performed within the first 6 months since the start of WP 5.2 of TECHNEAU integrated project and to give an overview of the results and future planning. This includes detailed regional investigations, field studies and laboratory work performed in collaboration between the KompetenzZentrum Wasser Berlin gGmbH (KWB), the Indian Institute of Technology in Delhi (IIT) and the Freie Universität Berlin (FUB). Preliminary studies at potential sites in different parts of the world were performed prior to the TECHNEAU Project with the aim to investigate their suitability for RBF and thus to allow for deeper investigation within TECHNEAU. These preliminary studies were carried out in the cities Kaliningrad (Russia), Recife (Brazil) and New Dehli (India), and were funded by Veolia Water. In Recife (Brazil), the investigation performed by the FUB showed that both hydrogelogical data and model results indicate that the area is not suitable for the production of drinking water by RBF in sufficient amounts due an unfavorable hydrogeological conditions (too low transmissivity of the target aquifer because of the low content of sand in the samples and the scarce distribution of sandy sediments). At this point further investigations were stopped since no alternative field site area was found. In Kalingrad, water quality data that was gained in the preliminary study from the field site and will be compared with the data gained from investigations in Delhi and Berlin. In Delhi, India, the appropriate conditions, as well as the establishment of a valuable collaboration with the IIT, has lead to the implementation of three different field sites (in three different conditions). The activity performed within the techneau framework and included (i) the integration of existing information and literature on local climate, geology and water supply system, (ii) the detailed investigation about the local hydrogeology and ground and surface water quality and (iii) the development of a GIS (Geo Information System). In agreement with local authorities, three different field sites were selected in the territory of Delhi, representing distinctly different environmental conditions within the district. According to local conditions, a net of 17 groundwater observation points (piezometers) has been designed and installed on each of the field sites. A description of local geology, including stratigraphical charts has been elaborated, based on the evaluation of information obtained during the drilling and from analysis of sediment samples. A strategy for monitoring of water level and water sampling analysis has been developed, and monthly field campaigns have been carried out. Water samples have been analyzed, considering a broad variety of parameters including major chemical contents, trace substances and pathogens. Hydraulic tests have been conducted to obtain aquifer properties in order to estimate travel velocities during underground passage.