This study investigates a post-denitrification process without the addition of an external carbon source combined with an enhanced biological phosphorus removal (EBPR) in a membrane bioreactor (MBR). Three trial plants, with two different process configurations, were operated on two different sites, and a variety of accompanying batch tests were conducted. It was shown that even without dosing of an external carbon source, denitrification rates (DNR) much above endogenous rates could be obtained in post-denitrification systems. Furthermore, the anaerobic reactor located a head of the process had a positive impact on the DNR. Given these surprising results, the project team decided to identify the carbon source used by the microorganisms in the postdenitrification process. Batch tests could demonstrate that lysis products do not play a major role as a C-source for postdenitrification. The following hypothesis was proposed to explain the observations: the glycogen, internally stored by the substrate accumulating bacteria, if anaerobic conditions are followed by aerobic conditions could act as carbon source for denitrification in post-denitrification system. First exploratory batch tests, where the glycogen evolution was monitored, corroborate this

The main goal of this project is to develop new sustainable sanitation concepts which have significant advantages in relation to ecological as well as to economical aspects compared to the conventional systems (end-of-pipe-system). After successful project completion the new sanitation concepts should be used in Berlin areas, where sewer systems are not installed and these concepts are appropriate, as well as other locations (national and international). The technical management of the project has been achieved as foreseen, but the administrative project manger has changed in July 2005 since the head of the Berlin Centre of Competence for Water has changed. All technical equipments, besides of the bio-gas plant, are realised. The bio-gas plant will be installed about the end of 2005. In contrary to the EU-proposal the concept with vacuum separation toilets has been installed for technical reasons in the office building instead in the apartment house. Before installing of these toilets gravity separation toilets have been operated for 1 ½ years. Furthermore not in 15 but in 10 flats of the apartment house was it possible to install gravity separation toilets. The addition tasks Life-Cycle-Assessment (Task 5), Industrial style urine treatment for utilization (Task 7) and Fertiliser usage (Task 8) undertaken by different Universities are in the works. The users accept the separation toilets in general, but more the gravity than the vacuum separation toilets. Both have to be improved, especially the flush. The worse assessment for the vacuum separation toilets was expected since they are altered gravity separation toilets. An optimised vacuum separation toilet is not available on the market at present. The results from the faeces separator show that far the most solids can be retained in the filter bags, but there is still a high solids-concentration in the filtrate. For huge settlements a different, continuously working separator is necessary. Due to the high solid concentration in the faecal filtrate the soil filter as a pre-treatment step was blocked very soon and went out of operation. With the 2-chamber septic tank for greywater and faecal filtrate treatment an effluent quality could be obtained which does not lead to clogging of the downstream constructed wetland. The results of the constructed wetland are as expected. From the work of Task 5 and the experiments of Task 7 no reliable results are available until now. The experiments of Task 8 show that the fertilising results from the urine are similar with those from mineral fertilisers. Until the end of the project the different tasks will continue. The digestion of the faeces from the vacuum separation toilets with the bio-gas plant will start in January 2006. In relation to the financial issues 790,482 € (51 %) of the total eligible costs of 1,552,116 € and 1,230,640 € (55 %) of the total real costs of 2,223,474 € respectively have been spent until now. Herewith, the 30 % threshold of the total real costs is transcended.

As part of the EU-Life ENREM demonstration project the Department of Chemical Engineering, TU Berlin, was appointed to conduct the preliminary pilot trials in a representative site for verification of basic process designs and operation criteria of the full-scale MBR demonstration plant. In addition to conception and construction of the pilot plant, this investigation consists of two successive trial phases with distinct operation conditions: the first one being dedicated to the assessment of the “irregular sludge wastage strategy” (the biomass is accumulating in the reactor, which is partly emptied when the sludge concentration reaches a given value), and the second one being planned to verify normal operation conditions with daily sludge wastage. This progress report describes implementation and results of the first phase, for which a pilot plant of 140L was operated over 6 months with waste water of a decentralized area. The influent contained high concentrations of nitrogen (100-200 mg/L), phosphorus (10- 20 mg/l) and COD (1000-2000 mg/L). Also surprising were the high VFA concentrations (100-300 mg/L) which ensured a good EBPR process. The COD and also the enhanced biological phosphorus removal (EBPR) were not impacted by the irregular sludge wastage. COD effluent concentrations were around 50 mg/L and TP effluent was 0.1 to 0.3 mg/L. The high nitrogen influent concentrations were problematic. Due to changing TS concentrations and changing nitrification rates TN effluent was 10 to 30 mg/L with a NH4-N content of 0 to 20 mg/L. Denitrification rates were measured between 1 and 3 mgN/gVS h and were depending on TS concentration, with higher rates at lower TS concentrations. Polysaccharide concentrations in the sludge water phase were higher with low TS concentrations and low oxygen concentrations. Higher PS values led to faster fouling. Results of the trials suggest that the oxygen concentration should be kept above 2mg/L to ensure both sufficient nitrification and lower fouling. Since also high TS concentrations are needed to ensure complete nutrients removal the optimum TS range is relatively small and it must be concluded that the irregular sludge wastage strategy was not beneficial in this case and the demonstration plant should be run with regular sludge removal.

The ENREM project aims at demonstrating a novel wastewater treatment process based on the technology of membrane bioreactor (MBR), set up in a configuration to enable enhanced biological elimination of nutrients. A new plant, and the related sewer system, is to be built in a yet unsewered remote area of Berlin. The plant will be then operated over more than one year, and the process will be optimised. Performances and costs of the treatment system will be then assessed for the size 250 – 10,000pe, corresponding to semi-central schemes. The management of the project has been achieved according to the organisation identified in the LIFE proposal. No relevant modification has been required. Annex 3.1 presents and discusses the key deliverables and milestones depending on the LIFE proposal and the current status. In relation to the technical content, Task 2 “Site and process definition” and Task 4 “Detailed design” are quasi-completed, with however a four month delay which will put back consequently the following actions, such as start of sewer and plant construction, and plant commissioning. Specifically, the following actions were completed, or are on the verge of completion: - Cost-comparison of decentralised treatment solutions to serve 20 unsewered areas of Berlin and selection of demonstration site (district of Margaretenhöhe); - Revision of cost evaluation for infrastructure; - Planning and specification of MBR plant; - Preparation and release of call for tender of MBR plant; - Planning and specification of low-pressure sewer; - Preparation and release of call for tender of low-pressure sewer construction; - Acquisition of legal permits (for plant construction & operation, water discharge); - Acquisition of parcel for MBR plant. In addition, the first trials phase of Task 3 “Preliminary testing on representative site” (period with irregular excess sludge withdrawal) was completed and enabled to validate the design criteria of the MBR demonstration plant. The relationship with the inhabitants of Margaretenhöhe was initiated in order to ensure a smooth construction phase, and a quick connection to the new sewer system. Dissemination activities were undertaken accordingly as shown in Annexes 7.1-7.3, and the project web-site in three languages was set up (see in www.kompetenz-wasser.de). The communications on project are expected to ramp up in 2005 and 2006, as more outcomes and results are getting available. The main task in 2005 will be the construction and commissioning of the low sewer system and the MBR demonstration plant. The start-up of the novel treatment scheme is now expected for October / November 2005. From the budget perspective, the total costs incurred over 2004 were 198,353€. This is 6% of the total budget of the LIFE proposal. The infrastructure costs and most of equipment costs (expected 62% of total budget) should occur in 2005 during the construction and commissioning phases of the scheme. No major budget deviation was noticed so far, and the re-evaluation of the infrastructure costs fit with those of the LIFE proposal.

Real-time control of urban drainage systems allows activating capacities of storm water storage and wastewater treatment that were not used before. The historically developed structure of the Berlin combined sewerage, along with its aforementioned properties, allows per se a systematic management of the sub-systems. In the course of rehabilitation works the implementation of local regulators already opened additional storage reserves. Additionally, the potential of global control concepts for sewerage, pump stations and treatment plants is studied within the framework of the project “Integrated Sewage Management” to increase the systems efficiency. Especially, a coordination of the currently locally controlled pump stations entails a reduction of sewer overflows and hence an enhanced protection of the environment. For the catchment of wwtp Berlin-Ruhleben an integrated model of the collection system, pump stations, pressurised mains and the wwtp itself has been built up in order to evaluate different scenarios of global pump station control in comparison to a local control scenario (reference). Special attention was paid to the discharges from CSOs. Due to the high dynamic of these events and the high fraction of biodegradable organic substrate within the effluents, the impact on the water body over this path plays an important role. Concerning CSOs a maximum reduction of 14 % (COD load) and 20 % (TKN load) could be achieved. In conclusion it can be stated that a reduction of total emissions from the sewage system can be achieved by operating the pump stations in a global control mode. Furthermore, the main improvement can be observed for the discharges from combined sewer overflows.

Residues of pharmaceuticals used in human medical care have recently been detected as important trace contaminants of sewage, surface and groundwater. This paper compiles the recent state of knowledge on the occurrence and fate of pharmaceutical residues in the aquatic environment of urban areas. Findings in sewage effluents, surface, ground, and drinking water at concentrations up to the µg/L-level have been reported and will be discussed to demonstrate the impact of pharmaceutical residues on the aquatic environment and on public water supply. The efficiency of natural and technological processes such as bank filtration or membrane filtration for the removal of pharmaceutical residues including estrogenic steroids, analgesics, antibiotics, anti-epileptic drugs, blood lipid regulators, and several drug metabolites will be presented and discussed.

Investigations on the behavior of different bulk organics and trace organic compounds at a bank filtration site at Lake Tegel in Berlin, Germany, and in a long retention soil column system are reported. Objective of the research was to assess important factors of influence for the degradation of bulk and trace organics. More than two years of monitoring for the bulk parameter DOC proved that the redox conditions significantly influence the DOC-degradation kinetic but not necessarily the residual concentration. LC-OCD measurements confirmed that the change in character is comparable for aerobic and anoxic/anaerobic infiltration. Only the fraction of polysaccharides shows a better removal under aerobic conditions. Furthermore, adsorbable organic iodine (AOI) measurements revealed a more efficient degradation of AOI and AOBr under anoxic/anaerobic conditions. The monitoring of the single organic pollutants Iopromide, Sulfamethoxazole and naphthalenedisulfonic acids showed that the redox conditions have an influence on the degradation behavior of some of the monitored compounds. Iopromide was efficiently removed at all times, but no evidence for a dehalogenation under oxic conditions was found. Sulfamethoxazole showed a better removal under anoxic/anaerobic conditions. The very stable 1.5naphthalenesulfonic acid was not removed under either redox conditions.

Im Rahmen dieser Diplomarbeit wurde das Berliner Abwassersystem hinsichtlich einer Abflusssteuerung untersucht. Auf Grundlage des Merkblattes DWA-M 180 wurde zunächst die formale Bewertung des Steuerungspotenzials des Berliner Mischsystems durchgeführt. Weiter wurde für Niederschlagsereignisse des Jahres 2003 eine statische Bilanzierung bezüglich anfallender Wassermengen und vorhandenem Speichervolumen aufgestellt. Anhand von ausgewählten Ereignisse wurden dann für verschiedene Szenarien die Auswirkungen einer geänderten Förderstrategie untersucht. Im Vordergrund standen eine gleichmäßige Nutzung der Systemkapazitäten, die Verringerung von Mischwasserentlastungen und die Reduzierung des Mischwasserabflusses zur Kläranlage.