The study aims at assessing in long-term trials a gravity-driven ultrafiltration pilot plant designed for a capacity of 5 m3/d. The unit was operated in South Africa with Ogunjini surface water and was run with restricted chemical intervention or maintenance (no backflush, no aeration, no crossflow and no chemical). Under South African environmental conditions and with direct filtration of the river water and only one manual drainage of the membrane reactor every weekday, the unit could fulfil the design specification in terms of water production (5 m3/d) as long as the turbidity of the raw water remained in a reasonable level (up to 160 NTU), with a filtration flux typically 4 to 6 L/h.m² (corrected at 20°C). This value was in the same range as the lab results and was consistent with the first phase results (around 5-7 L/h.m² after biosand filtration). However, the flux dropped significantly to a range of 2 to 4 L/h.m² after a rain event resulting in a turbidity peak over several days up to > 600 NTU. This demonstrated that for variable raw water types with expected turbidity peaks above 100 NTU, a pre-treatment would be required for the system (biosand filter or other). The performance of microbiological tests confirmed the integrity of the membrane and the ability of the system to achieve advanced disinfection.

Bank filtration (BF) and aquifer recharge (AR): aquifer storage recharge (ASR), aquifer storage transport recharge (ASTR); are natural and semi-natural methods for drinking water treatment and constitute a major barrier within water supply system. Recent investigations have shown that about 60 % of Berlin’s drinking water is produced via BF or AR (Zippel & Hannappel 2008). Most drinking water therefore originates from surface waters within the cities limits and is pumped from wells adjacent to it’s many lakes and rivers. Since more than 100 years this system has been supplying safe drinking water so that post-treatment is limited to aeration and subsequent sand filtration. Disinfection is usually not applied (SenStadtUm 2008). The research project NASRI (“Natural and Artificial Systems for Recharge and Infiltration”, KWB 2002 – 2006), funded by the Berliner Wasserbetriebe (BWB) and Veolia (VE) had the aim to characterize the specific hydraulic and hydrochemical conditions at selected BF and AR sites in Berlin and to assess the behaviour of major water constituents, trace organic substances, algal toxins and pathogens during subsurface passage. For this, field investigations at three transsects (Lake Tegel BFsite, Lake Tegel AR-site and Lake Wannsee), laboratory and technical scale experiments were carried out by 7 different working groups. The results of the investigations were documented in 6 extensive research reports and were the basis for nearly 50 scientific publications. In 2007 the IC-NASRI project (Integration & Consolidation of the NASRI outcomes) was initiated by VE and BWB in order to support the practical implementation and optimization of bank filtration and aquifer recharge for drinking water production with the experience gained during the NASRI project. The aim was to derive practical guidelines for design and operation of BF & AR systems by i) further interpretation of the NASRI data and ii) integrating experience from other BF / AR sites world wide. Although subsurface passage is characteristic to many systems of managed aquifer recharge (MAR) the investigations within IC-NASRI concentrated on systems where drinking water is produced by infiltration of surface water either from the banks of a lake / river or from infiltration ponds (or similar systems like ditches or irrigation fields). A transfer of the presented results to other MAR systems, which use different recharge methods (e.g. ASR) or different sources (e.g. treated wastewater) therefore needs to be considered carefully, even though many statements may be true for them as well. This reports aims at providing engineers and scientists involved in drinking water production by BF & AR with up-to-date information on settings of similar systems world wide and on the systems’ performance with regard to drinking water treatment. The aim was to give the reader a condensed overview of the topic whereas further details can be taken from the large number of references given in the bibliography.

Within the study “IC-Pharma” a graphical benchmark of the occurrence of 30 priority pharmaceutical active compounds (PhACs) covering different therapeutic classes such as analgesics, antibiotics, lipid lowering drugs, beta blockers, tranquilizers, and cytostatics in the urban water cycle was conducted. The results are based on an extensive data set collected during several monitoring campaigns in Berlin and the Canton Zurich. This benchmark of the occurrence of priority pharmaceuticals allows water practitioners from other sites to compare detected concentrations of priority PhACs in STP effluents, surface water and groundwater.

The project OXIRED was initiated to assess the potential of a combination of natural systems such as bank filtration (BF) and artificial recharge (AR) and oxidation processes in order to improve the degradability of DOC and the removal of trace organics during water treatment. In this literature study, treatment schemes, which combine subsurface passage with oxidation processes, were evaluated with regard to the potential removal of DOC and trace organics, by theoretical considerations and case study analyses. The objectives were i) to estimate the degradation of bulk organic matter and trace organics in such combined systems, ii) to assess the potential for toxic by-products and iii) to describe different possible schemes combining natural systems (BF & AR) and oxidation processes. Available data generally shows good removal of the substances identified as persistent during BF & AR by oxidation processes. Carbamazepine, for example, is poorly degradable during bank filtration, but ozonation leads to a transformation of more than 97%. If ozonation alone does not suffice, advanced oxidation processes may enhance the transformation. E.g. literature gives a values of < 50% removal of Iopamidol by ozonation. However, transformation increases up to 88% using advanced oxidation processes, such as O3/H2O2 and O3/UV. Investigations on the formation of possible toxic by-products have shown the general possibilities to control the formation of bromate by decreasing the pH, avoiding free dissolved ozone in the reactor and/or by adding H2O2. Only a low risk of exposure of the potentially forming nitrosamines in drinking water after artificial recharge could be identified. Especially the cancerogenic metabolite NDMA is degraded during subsurface passage. Three reference treatment schemes were identified: (A): surface water is treated via oxidation before infiltration into artificial recharge ponds.(B): a river bank filtration with short retention times (<5 days) is used as a pretreatment step before the successive oxidation and artificial recharge (AR). (C1/C2): oxidation is applied subsequent to subsurface passage after bank filtration and artificial recharge. Due to the possible formation of toxic by-products and the increased assimilable DOC in scheme C (Examples for C1 Mülheim Styrum-East and Le Pecq Croissy & C2 Prairie Waters Project and the Bi´eau Process) a post-treatment including disinfection after oxidation is necessary. Additional post-treatment in schemes A (implemented at Mülheim Dohne) and B depends on the redox conditions and the travel times during the subsurface passage. However, although there is a lack of practical data, the enhancement of BDOC via oxidation prior to the underground passage seems theoretically more promising than the reverse configuration. It is therefore recommended that any further experimental program in OXIRED should focus on the schemes A and B and include a cost-benefit analysis of the additional first BF step.

The study aims at assessing in long-term trials a gravity-driven ultrafiltration pilot plant designed for a capacity of 5 m3/d. The unit was operated in South Africa with Ogunjini surface water and was run with restricted chemical intervention or maintenance (no backflush, no aeration, no crossflow and no chemical). Under South African environmental conditions and with direct filtration of the river water and only one manual drainage of the membrane reactor every weekday, the unit could fulfil the design specification in terms of water production (5 m3/d) as long as the turbidity of the raw water remained in a reasonable level (up to 160 NTU), with a filtration flux typically 4 to 6 L/h.m² (corrected at 20°C). This value was in the same range as the lab results and was consistent with the first phase results (around 5-7 L/h.m² after biosand filtration). However, the flux dropped significantly to a range of 2 to 4 L/h.m² after a rain event resulting in a turbidity peak over several days up to > 600 NTU. This demonstrated that for variable raw water types with expected turbidity peaks above 100 NTU, a pre-treatment would be required for the system (biosand filter or other). The performance of microbiological tests confirmed the integrity of the membrane and the ability of the system to achieve complete disinfection.

This report presented recent developments in the field on the UV-LED disinfection. This technological field is very recent and further interests - along with rapid and continuing improvements in performance (especially in terms of emission power) - are expected within the next years. After the physical characterisation of the few UV-LEDs - at 269 and 282 nm - that are currently available on the market, their disinfecting action was to be measured via biodosimetric tests. They show an increase of the inactivationwith an increasing fluence using different types of raw water, although some early static tests tend to highlight potential recontamination and inhomogeneous distribution of UV-light - which may be explained by the module configuration. Main other results indicate that UV-absorbing compounds in the various waters reduce the disinfection capacity. Morevoer, a more effective disinfection is observed at 269 nm than at 282 nm for a similar fluence. However, the emission output is better with 282 nm - UV-LEDs. Therefore, an interesting aspect, worth being investigated in the future is to ensure an optimized configuration, which balances the input power, which is necessay to run the UV-LED module, and its disinfecting action. With potential enhanced emission powers, new developments for UV-LED water purification applications would enable to perform larger-scale tests and shorten UV exposure times.

Rver Bank Filtration (RBF) is a drinking water (pre-)treatment that can remove a wide variety of surface water contaminants . However, the efficiency of this natural treatment process depends on hydrochemical, aquifer- and operational characteristics. Therefore, complementary treatment options may be required in order to build up a multiple-barrier-system and obtain drinking water quality. As a follow-up to the TECHNEAU WP5.2 field investigations, this report aims at identifying potential post-treatment schemes for drinking water production at three river bank filtration sites in New Delhi - Palla, Nizamuddin and Najarfgarh – for which physicochemical parameters as well as levels of inorganic and trace organic substances and microbial contamination have been measured during field campaigns in 2007 and 2008 (see deliverables D5.2.2 and D5.2.6). The three investigated RBF sites in Delhi have distinctive geographical locations and contamination exposures. For each of them, critical water parameters were identified that present a challenge with regards to drinking water production, for which different treatment technologies are envisaged (see table below). For Palla and Najafgarh, one specific water component (fluoride and salinity, respectively) requires targeted treatment. For Nizamuddinm, however, where surface water is highly exposed to contamination from poorly treated waste water, theoretical post-treatment options are no longer efficient and extensive conventional wastewater treatment is recommended. One other possible option for Nizamuddin is the Oxidation / Biofiltration / Membrane technology (OBM process) developed by NTNU and SINTEF within the TECHNEAU project and a specific report on its application to Delhi is planned within TECHNEAU WP7.9. This report shows the theoretical post-treatment options for river bank filtration sites in Delhi. The strong technological requirements for Nizamuddin and Najafgarh seem inadequate to be currently implemented. The priority in Delhi would be to develop an integrated water and wastewater management, in order to reduce contamination in the surface water and thereby lower the technological requirements for drinking water production.

The study aims at validating the point-of-use investigations on long-term gravity-driven ultrafiltration for a scaled-up system, which could produce drinking water for a community of 100-200 inhabitants using natural surface water. Eawag, KWB and Opalium conceived a membrane-based small-scale system (SSS) which can operate without crossflow, backflush, aeration or chemical cleaning. Equipped with a biosand filter as pretreatment, it is designed to be robust, energy-sufficient (gravity-driven) and run with restricted chemical intervention (only residual chlorine). The containerised unit (10’) requires to be fed with raw water at a 2 m-height (energy-equivalent to ~8Wh/m3). As sole operational requirement, the membrane reactor is simply to be drained (i.e. emptied) on daily to weekly basis to superficially remove the material retained by the membrane and accumulated in the module. Otherwise, the system, which is only driven by a 40 cm differential pressure head (i.e. 40 mbar), is totally self-determined and autonomous. This report details the validation tests performed at Veolia Water Research Center in Annet-sur-Marne (France) from January to August 2009 : the gravity-driven UF compact unit showed promising results in regards to flux stabilization and flow capacity. Although early investigations take place in winter, an initial flux stabilization to 2.5 lmh is observed, which is below the reference results from the Eawag lab tests (i.e. 7-10 lmh, at 20 ± 2°C). However, the “scaled-up” system can benefit from a weekly drainage which seems to enhance the flux to 4-5 lmh, and thereby, the unit is to produce more than 4 m3/d, which is consistent with the design target of 5 m3/d. Moreover, the increase of the drainage frequency (to 3 times/week) along with warmer temperatures – leading to a better membrane permeability and biological activity - contribute to a further enhancement to 5-7 lmh. This is particularly relevant for South Africa, for which decentralized water supply is a burning issue and where the unit is to be further tested from November 2009. The investigations also highlighted the critical performance of the biosand filter as pretreatment. More than the UF step – whose membrane integrity was confirmed with bacterial analyses, the pretreatment step needed more frequent (i.e. monthly) O&M requirements. Therefore, the pretreatment necessity will be further assessed in South Africa where high turbidity peaks could represent an extra challenge for the unit.

Membrane processes stand as a promising technology to ensure a safe water supply at the community and the household levels. As the price of membranes has notably decreased over the last years, the market of membrane-based systems for decentralised applications has developed and diversified. In order to have a view of what the current market offers, 204 water companies were contacted and asked to characterise their Point-of-use (POU) or small-scale membrane systems, with a focus set on operation and maintenance, costs and energy requirements. Such study was not performed previously. With a 15% reply rate, the survey enables to identify the different market niches. That includes ceramic POU, organic POU, organic point-of-entries (POE), modular treatment units and emergency systems, whose technical characterization is further detailed in the Annex. Besides, the review of the marketed membrane modules reveals that ultrafiltration is the most available process. The survey also shows that the pre-treatment is a key parameter when considering options for decentralised water supply. As needs for sustainable solutions for small water supply are established, the membrane market is expected to grow and more standardised products to appear. The market evaluation can be summarized in Figure 1. Depending on the product niche, the membrane material and the filtration type, different degrees toward the market maturity are then highlighted. Such systems would be broadly applied in developed countries, but they represent also great potential for transition and developing countries. However, few systems designed for long-term operation with low-energy and low-chemical requirements exist yet. Therefore, the R&D identified within Techneau matches a non-fulfilled yet requirement.